HMX !mnemonic for mixture model, must match hfmix on call to SETUP ! compiled by M. McLinden, NIST Thermophysics Division, Boulder, Colorado ! 01-08-96 MM, original version ! 05-06-96 MM, rearrange sequence of parameters: Kt, Kv first ! add new model MKT: Tc by geometric mean, Kt is only parameter ! 05-08-96 MM, add descriptors for binary-specific parameters ! 05-10-96 MM, add default (ideal-solution) values for binary parameters ! 05-29-96 MM, add LJ1, LJ2, LJ3 from Lemmon's thesis ! 06-10-96 MM, add binary coefficients from Lemmon's thesis; change MKT to VDW ! 06-12-96 MM, replace LJi rule with modified L-J (LMi) for several mixtures ! 07-01-96 MM, tranform R32-specific terms in LM2, LM3 into LM1 form ! 10-11-96 MM, add parameters for R32/143a, R125/143a, R143a/134a ! 10-18-96 MM, add parameters for R32/propane, R125/propane, propane/R134a ! 11-04-96 MM, replace van der Waals with linear rule, expand binary par to 6 ! 11-06-96 MM, revise Kt, Kv to conform with linear mixing rule, ! revise parameters specific to R32 mixtures (LM2 and LM3) ! 11-14-96 MM, add R41/CO2 parameters, add LM9 model ! 11-19-96 MM, add parameters for critical line (dummy coeff for now) ! 11-27-96 MM, add critical line parameters, values fitted by E. Lemmon ! 05-21-97 MM, update mixture-specific generalized parameters rec'd from EWL 5-8-97 ! add remaining binaries from EWL thesis (but don't have critical lines yet) ! 05-22-97 MM, change format for coeff to f12.x ! 05-23-97 MM, update coefficients using values from EWL rec'd 5-8-97 ! 06-05-97 EWL, update coefficients, correct gamma = 0 to gamma = 1 ! 07-11-97 MM, had incorrect CAS # for R152a, affected R12/152a (R500), R22/152a, R134a/152a ! 11-12-97 MM, add 60 mixtures fitted by E.W. Lemmon ! 11-14-97 MM, add critical line fits by E.W. Lemmon for the above 60 binary mixtures #BNC !binary mixing coefficients BNC ?binary mixing coefficients for the various mixing rules used with the HMX model ?LJi: (i = 1,2,3) ? CAS 1 CAS 2 model zeta xi Fpq beta gamma not used ? ?LMi: (i = 1,2,3) ? CAS 1 CAS 2 model Kt Kv Fpq beta gamma not used ? ?TR1: ? CAS 1 CAS 2 model Kv alpha not used not used not used not used ? ?LIN: ? CAS 1 CAS 2 model Kt Kv not used not used not used not used ? ?coefficients for binary critical lines ? TC1: Tc = x1*Tc1 + x2*Tc2 + x2*(a1*x1 + a2*x1**2 + a3*x1**3 + a4*x1**4 + a5*x1**5 + a6*x1**6) ? model a1 a2 a3 a4 a5 a6 ? ? VC1: Vc = x1*Vc1 + x2*Vc2 + x2*(a1*x1 + a2*x1**2 + a3*x1**3 + a4*x1**4 + a5*x1**5 + a6*x1**6) ? model a1 a2 a3 a4 a5 a6 ? ? N.B. format for a binary pair must be: ? line 1: comments beginning with '?' (these are read by Fortran and displayed by GUI) ? 2: additional comments beginning with '?' (not read) ? 3: CAS_1, CAS_2, model, (binary parameters) in format: (a12,1x,a12,1x,a3,1x,6f12.x) ? 4: model, (Tc line parameters) in format: (26x,a3,1x,6f12.x) ? 5: model, (Vc line parameters) in format: (26x,a3,1x,6f12.x) ? 6: separator line ('!') ? ! ?methane /ethane ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /74-84-0 LJ1 0.0000000 0.0000000 1.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /propane ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /74-98-6 LJ1 19.3902890 -0.0026691 1.5563610 1.8822660 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /butane ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /106-97-8 LJ1 41.1329920 0.0000000 2.4454150 2.0066730 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /isobutane ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /75-28-5 LJ1 40.0392170 0.0000000 2.6616640 2.5444090 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /nitrogen ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /7727-37-9 LJ1 -17.8186760 0.0038104 0.6341820 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /124-38-9 LJ1 -37.2711800 0.0000000 0.8085460 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?ethane /propane ?Lemmon (1996), PhD thesis, U. Idaho 74-84-0 /74-98-6 LJ1 2.7212970 -0.0065622 -0.0309970 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?ethane /butane ?Lemmon (1996), PhD thesis, U. Idaho 74-84-0 /106-97-8 LJ1 0.0000000 0.0000000 0.7595280 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?ethane /isobutane ?Lemmon (1996), PhD thesis, U. Idaho 74-84-0 /75-28-5 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?ethane /nitrogen ?Lemmon (1996), PhD thesis, U. Idaho 74-84-0 /7727-37-9 LJ1 -17.7798630 0.0097502 1.0210550 1.2335390 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?ethane /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 74-84-0 /124-38-9 LJ1 -63.6296720 0.0095200 -0.1541270 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?propane/n-butane (R290/600) based on PVT data of Parrish (RMS dev = 0.06%) ?Lemmon (1996), PhD thesis, U. Idaho 74-98-6 /106-97-8 LM1 1.0000000 1.0000000 0.2680600 1.000000 1.000000 0.000000 TC1 7.5389000 5.9013700 0.0000000 0.000000 0.000000 0.000000 VC1 -0.0064800 0.0571800 -0.0287400 0.000000 0.000000 0.000000 ! ?propane/isobutane (R290/600a) based on PVT data of Kahre (RMS dev = 0.30%) ?Lemmon (1996), PhD thesis, U. Idaho 74-98-6 /75-28-5 LM1 1.0000000 1.0000000 0.1315200 1.000000 1.000000 0.000000 TC1 6.8582600 0.0000000 0.0000000 0.000000 0.000000 0.000000 VC1 0.0122100 0.0147900 -0.0053800 0.000000 0.000000 0.000000 ! ?propane /nitrogen ?Lemmon (1996), PhD thesis, U. Idaho 74-98-6 /7727-37-9 LJ1 -22.3391550 0.0095280 1.8949610 4.3677400 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?propane /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 74-98-6 /124-38-9 LJ1 -48.8205560 0.0000000 -0.4356170 0.7269760 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?n-butane/isobutane (R600/600a) based on PVT data of Kahre (RMS dev = 0.02%) ?Lemmon (1996), PhD thesis, U. Idaho 106-97-8 /75-28-5 LM1 1.0000000 1.0000000 0.0363300 1.000000 1.000000 0.000000 TC1 0.8847900 0.0000000 0.0000000 0.000000 0.000000 0.000000 VC1 -0.0025800 0.0005000 0.0000000 0.000000 0.000000 0.000000 ! ?butane /nitrogen ?Lemmon (1996), PhD thesis, U. Idaho 106-97-8 /7727-37-9 LJ1 112.8092200 -0.0250613 -2.3100960 1.1940890 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?butane /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 106-97-8 /124-38-9 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?isobutane/nitrogen ?Lemmon (1996), PhD thesis, U. Idaho 75-28-5 /7727-37-9 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?isobutane/CO2 ?Lemmon (1996), PhD thesis, U. Idaho 75-28-5 /124-38-9 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?nitrogen /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 7727-37-9 /124-38-9 LJ1 -31.1493000 0.0065998 2.7806470 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?nitrogen /argon ?Lemmon (1996), PhD thesis, U. Idaho 7727-37-9 /7440-37-1 LJ1 -3.1060410 0.0000000 -0.0285420 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?nitrogen /oxygen ?Lemmon (1996), PhD thesis, U. Idaho 7727-37-9 /7782-44-7 LJ1 -2.3253820 0.0000000 0.1160000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?nitrogen /neon ?Lemmon (1996), PhD thesis, U. Idaho 7727-37-9 /7440-01-9 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?argon /oxygen ?Lemmon (1996), PhD thesis, U. Idaho 7440-37-1 /7782-44-7 LJ1 0.0000000 0.0000000 -0.3603850 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?argon /neon ?Lemmon (1996), PhD thesis, U. Idaho 7440-37-1 /7440-01-9 LJ1 0.0000000 0.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?argon /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 7440-37-1 /124-38-9 LJ1 0.0000000 0.0000000 -0.1381730 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?neon /CO2 ?Lemmon (1996), PhD thesis, U. Idaho 7440-01-9 /124-38-9 LJ1 0.0000000 0.0000000 1.2072810 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /argon ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /7440-37-1 LJ1 6.8669160 0.0000000 -1.1373310 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?methane /ethylene ?Lemmon (1996), PhD thesis, U. Idaho 74-82-8 /74-85-1 LJ1 -11.0710050 0.0000000 0.7428360 1.0000000 1.0000000 0.0000000 TC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 ! ?R32/125 based on PVT data of Magee (RMS dev = 0.22%), Kleemis (0.16%); VLE of Defibaugh (0.28%), Kleemis (0.60%) ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 351.255 8.15008 339.330 4.75996 75-10-5 /354-33-6 LM2 1.0424666 0.9681369 -0.7895850 1.0000000 1.0000000 0.0000000 TC1 -15.1301300 -10.2922500 17.2799800 -19.5658600 0.0000000 0.0000000 VC1 -0.0135300 -0.5674000 2.0040800 -3.5757400 3.3101100 -1.3278200 ! ?R32/134a based on PVT data of Magee (RMS dev = 0.26%), Kleemis (2 sets 0.12% & 0.05%), Sato (1.27%), Widiatmo (0.11%); VLE of Defibaugh (0.37%), Kleemis (0.26%) ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 351.255 8.15008 374.210 5.01705 75-10-5 /811-97-2 LM3 1.0158192 0.9757677 -0.3145740 1.0000000 1.0000000 0.0000000 TC1 7.2676800 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0097000 0.0842100 -0.5093300 1.0573000 -0.9937000 0.3555600 ! ?R125/134a based on PVT data of Magee (RMS dev = 0.14%); VLE of Kleemis (0.71%) ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 339.330 4.75996 374.210 5.01705 354-33-6 /811-97-2 LM1 0.9923285 1.0000000 0.1047290 1.0000000 1.0000000 0.0000000 TC1 0.7594900 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0364100 0.2280100 -0.8166000 1.4644900 -1.2832900 0.4375100 ! ?R134a/152a based on PVT data of Tillner-Roth (RMS dev = 0.14%) ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 374.210 5.01705 386.411 5.57145 811-97-2 /75-37-6 LM1 0.9946327 1.0257611 0.1259970 1.0000000 1.0000000 0.0000000 TC1 -4.4143900 -0.0385400 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.1121700 -0.6041900 2.1764400 -3.8841200 3.3592000 -1.1809300 ! ?R32/143a based on experimental VLE and PVT data; ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 351.255 8.15008 346.040 5.15112 75-10-5 /420-46-2 LM1 0.9519422 1.0000000 -0.1241740 1.0000000 1.0000000 0.0000000 TC1 -11.0115700 -6.2977500 3.2022400 0.0000000 0.0000000 0.0000000 VC1 0.0217200 -0.0375200 0.0369000 -0.0170300 0.0000000 0.0000000 ! ?R125/143a based on experimental VLE and PVT data; ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 339.330 4.75996 346.040 5.15112 354-33-6 /420-46-2 LM1 1.0080094 1.0000000 0.0167670 1.0000000 1.0000000 0.0000000 TC1 2.4260000 0.3129800 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0005300 -0.0009500 0.0000000 0.0000000 0.0000000 0.0000000 ! ?R134a/143a based on experimental VLE and PVT data; ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 374.210 5.01705 346.040 5.15112 811-97-2 /420-46-2 LM1 1.0021335 1.0055486 0.0539200 1.0000000 1.0000000 0.0000000 TC1 3.6642500 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0057700 -0.0362500 0.2581700 -0.7308500 0.9286100 -0.4466500 ! ?propane/R32 based on experimental VLE data ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 369.850 5.00000 351.255 8.15008 74-98-6 /75-10-5 LM1 0.7586413 0.9395164 -1.1135260 1.0000000 1.0000000 0.0000000 TC1 -49.0856600 -145.8900 297.160000 -106.130000 0.0000000 0.0000000 VC1 -0.0257100 -0.0443400 0.5602900 -1.0759700 0.2881000 0.4250500 ! ?propane/R125 based on experimental VLE data ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 369.850 5.00000 339.330 4.75996 74-98-6 /354-33-6 LM1 0.8020856 1.0508648 -0.4849370 1.0000000 1.0000000 0.0000000 TC1 -52.0372400 -75.4711700 148.5900 -52.3870500 0.0000000 0.0000000 VC1 0.0075700 -0.1023600 0.7981600 -2.3802300 2.6020800 -0.9473700 ! ?propane/R134a based on experimental VLE data ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 369.850 5.00000 374.210 5.01705 74-98-6 /811-97-2 LM1 0.9182995 1.1117017 -3.4374170 1.0000000 1.0000000 0.0000000 TC1 54.8574100 -190.730000 341.9000 -300.3400 133.890000 0.0000000 VC1 0.0368100 -0.1869100 0.5485900 -0.7265000 0.3712100 0.0000000 ! ?CO2/R41 based on experimental VLE and PVT data; ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using critical T and rho of: 304.210 10.60000 317.280 9.30000 124-38-9 /593-53-3 LM9 1.0870700 0.9395524 -0.5028060 1.0000000 1.0000000 0.0000000 TC1 2.1603500 -34.4268300 21.9341500 0.0000000 0.0000000 0.0000000 VC1 -0.0015800 -0.0512100 0.0000000 0.0000000 0.0000000 0.0000000 ! ?propane /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.850 5.00000 369.295 6.05822 74-98-6 /75-45-6 LM1 0.8824703 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -38.3309524 -29.3828489 47.2325953 -13.7255295 0.0000000 0.0000000 VC1 -0.0297075 0.1172474 -0.1123465 0.0245808 0.0000000 0.0000000 ! ?propane /R115 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.850 5.00000 353.100 3.96914 74-98-6 /76-15-3 LM1 0.8860522 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -36.5120137 -19.5193336 20.4980559 0.0000000 0.0000000 0.0000000 VC1 0.0247598 -0.0357387 -0.0387930 0.0000000 0.0000000 0.0000000 ! ?propylen /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 385.120 4.67278 115-07-1 /75-71-8 LM1 0.9766949 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -2.6318676 -5.0421045 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0060211 -0.0134516 0.0103655 0.0000000 0.0000000 0.0000000 ! ?R13 /propylen fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 302.350 5.50934 365.570 5.30860 75-72-9 /115-07-1 LM1 0.9066303 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.7205970 -41.0552434 24.1042677 0.0000000 0.0000000 0.0000000 VC1 -0.0366474 -0.0196483 0.0694170 0.0000000 0.0000000 0.0000000 ! ?propylen /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 369.295 6.05822 115-07-1 /75-45-6 LM1 0.9568383 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -15.7252518 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0046464 0.0146734 -0.0108518 0.0000000 0.0000000 0.0000000 ! ?R23 /propylen fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 365.570 5.30860 75-46-7 /115-07-1 LM1 0.8129864 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 4.7110909 -88.7920225 26.0042735 0.0000000 0.0000000 0.0000000 VC1 -0.0335571 -0.1385644 0.3282585 -0.1292909 0.0000000 0.0000000 ! ?propylen /R114 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 418.830 3.39320 115-07-1 /76-14-2 LM1 0.9442251 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 35.2662088 -115.2665 151.0787 -79.1362304 0.0000000 0.0000000 VC1 0.0711826 -0.3016631 0.4669332 -0.2274534 0.0000000 0.0000000 ! ?propylen /R115 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 353.100 3.96914 115-07-1 /76-15-3 LM1 0.8856552 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -33.4702535 -24.4927096 19.6176116 0.0000000 0.0000000 0.0000000 VC1 0.0325790 -0.0444668 -0.0131777 0.0000000 0.0000000 0.0000000 ! ?propylen /R134a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 374.180 4.97883 115-07-1 /811-97-2 LM1 0.8729898 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -27.7162530 -54.7721072 38.8425527 0.0000000 0.0000000 0.0000000 VC1 0.0037707 -0.1286196 0.5362718 -0.7397043 0.3185271 0.0000000 ! ?propylen /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 410.250 4.32857 115-07-1 /75-68-3 LM1 0.9792790 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 11.5765214 -11.1045742 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0091330 -0.0041497 0.0099600 0.0000000 0.0000000 0.0000000 ! ?propylen /R152a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 365.570 5.30860 386.411 5.57145 115-07-1 /75-37-6 LM1 0.8992451 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -18.5687087 -46.8204879 28.5540334 0.0000000 0.0000000 0.0000000 VC1 0.0724324 -0.6741545 2.3781347 -4.0213375 3.3286663 -1.0902761 ! ?CO2 /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 304.210 10.60000 369.295 6.05822 124-38-9 /75-45-6 LM1 0.9981630 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 39.0037218 -7.6387014 20.2753156 0.0000000 0.0000000 0.0000000 VC1 0.0614906 -0.2411620 0.3736747 -0.1979950 0.0000000 0.0000000 ! ?R23 /CO2 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 304.210 10.60000 75-46-7 /124-38-9 LM1 0.9593478 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -9.7668903 -16.9435950 84.4856920 -144.2995 89.8021506 0.0000000 VC1 0.0095741 -0.0114188 0.0169941 0.0000000 0.0000000 0.0000000 ! ?CO2 /R32 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 304.210 10.60000 351.255 8.15008 124-38-9 /75-10-5 LM1 0.9904684 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 19.9605978 -1.8379965 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0352326 -0.1395334 0.2091404 -0.1085299 0.0000000 0.0000000 ! ?CO2 /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 304.210 10.60000 410.250 4.32857 124-38-9 /75-68-3 LM1 0.9556582 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 96.4602827 -91.7105975 98.7101267 0.0000000 0.0000000 0.0000000 VC1 0.0160694 -0.2745770 0.5038685 -0.2473270 0.0000000 0.0000000 ! ?R12 /R11 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 471.110 4.03296 75-71-8 /75-69-4 LM1 0.9987588 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 21.6418750 12.1555298 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0249419 -0.0087188 0.0463983 -0.0552150 0.0000000 0.0000000 ! ?R13 /R11 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 302.350 5.50934 471.110 4.03296 75-72-9 /75-69-4 LM1 0.9796608 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 98.7845238 -23.1482084 31.6423857 0.0000000 0.0000000 0.0000000 VC1 -0.0151421 -0.3851214 0.6720605 -0.5272656 0.0000000 0.0000000 ! ?R22 /R11 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 471.110 4.03296 75-45-6 /75-69-4 LM1 0.9360067 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 33.3562134 -15.2450838 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0017580 -0.0936527 0.0961513 0.0000000 0.0000000 0.0000000 ! ?R23 /R11 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 471.110 4.03296 75-46-7 /75-69-4 LM1 0.8253411 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 132.5425 -103.1159 -15.5337162 0.0000000 0.0000000 0.0000000 VC1 -0.0223705 -0.3592320 0.2869346 0.0000000 0.0000000 0.0000000 ! ?R13 /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 302.350 5.50934 385.120 4.67278 75-72-9 /75-71-8 LM1 0.9608873 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 38.0083507 -47.1465657 32.5425505 0.0000000 0.0000000 0.0000000 VC1 0.0034114 -0.0908825 0.0487233 0.0187018 0.0000000 0.0000000 ! ?R22 /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 385.120 4.67278 75-45-6 /75-71-8 LM1 0.9455796 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -10.8988998 -10.3721005 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0096568 -0.0091258 0.0165819 0.0000000 0.0000000 0.0000000 ! ?R23 /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 385.120 4.67278 75-46-7 /75-71-8 LM1 0.8385217 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 50.2774890 -116.8344 31.5632774 0.0000000 0.0000000 0.0000000 VC1 0.0149893 -0.2209569 0.2358182 0.0000000 0.0000000 0.0000000 ! ?R32 /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 351.255 8.15008 385.120 4.67278 75-10-5 /75-71-8 LM1 0.8045256 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -3.4343467 -128.3520 56.3542176 0.0000000 0.0000000 0.0000000 VC1 0.0010646 -0.0369069 0.0849984 0.0000000 0.0000000 0.0000000 ! ?R12 /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 487.210 2.98866 75-71-8 /76-13-1 LM1 1.0462171 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 61.7314815 2.1385776 47.3415437 0.0000000 0.0000000 0.0000000 VC1 0.0417047 -0.2348118 0.3812430 -0.2543047 0.0000000 0.0000000 ! ?R12 /R114 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 418.830 3.39320 75-71-8 /76-14-2 LM1 0.9949314 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 25.1535452 -43.3860193 35.8965526 0.0000000 0.0000000 0.0000000 VC1 0.0427516 -0.0934434 0.0723302 0.0000000 0.0000000 0.0000000 ! ?R12 /R134a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 374.180 4.97883 75-71-8 /811-97-2 LM1 0.8806725 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -39.8265351 -28.4942759 38.2680562 0.0000000 0.0000000 0.0000000 VC1 -0.0356978 0.1811019 -0.3192070 0.1635221 0.0000000 0.0000000 ! ?R12 /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 410.250 4.32857 75-71-8 /75-68-3 LM1 0.9440878 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -11.1659792 -12.5834005 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0160502 0.0263034 -0.0073131 0.0000000 0.0000000 0.0000000 ! ?R143a /R12 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 346.040 5.15112 385.120 4.67278 420-46-2 /75-71-8 LM1 0.9063868 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -13.4479616 -24.6102515 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0153705 -0.0076168 0.0280141 0.0000000 0.0000000 0.0000000 ! ?R12 /R152a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 385.120 4.67278 386.411 5.57145 75-71-8 /75-37-6 LM1 0.8851736 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -35.7414504 -35.4405525 37.9875651 0.0000000 0.0000000 0.0000000 VC1 0.0136560 -0.0138310 0.0020300 0.0000000 0.0000000 0.0000000 ! ?R14 /R13 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 227.510 7.10942 302.350 5.50934 75-73-0 /75-72-9 LM1 0.9657305 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 36.5876578 -29.0235271 15.4280074 0.0000000 0.0000000 0.0000000 VC1 0.0105728 -0.1790214 0.2680641 -0.1748020 0.0000000 0.0000000 ! ?R23 /R13 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 302.350 5.50934 75-46-7 /75-72-9 LM1 0.8658119 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -7.4355431 -157.9824 370.2034 -441.2586 214.8385 0.0000000 VC1 0.0101262 -0.0055955 -0.0024284 0.0000000 0.0000000 0.0000000 ! ?R13 /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 302.350 5.50934 487.210 2.98866 75-72-9 /76-13-1 LM1 1.0321908 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 150.4986 -11.1010537 60.2441723 0.0000000 0.0000000 0.0000000 VC1 0.0456502 -0.7008364 1.3066443 -1.0208940 0.0000000 0.0000000 ! ?R14 /R23 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 227.510 7.10942 299.070 7.49900 75-73-0 /75-46-7 LM1 0.8757896 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 21.9211885 -49.4054283 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0204319 -0.1658651 0.2214427 -0.0671657 0.0000000 0.0000000 ! ?R114 /R21 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 418.830 3.39320 451.480 5.11077 76-14-2 /75-43-4 LM1 0.9204674 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -5.4250920 -175.8445 520.0526 -704.8842 367.8949 0.0000000 VC1 0.0000126 -0.0275387 0.0734852 0.0000000 0.0000000 0.0000000 ! ?R23 /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 369.295 6.05822 75-46-7 /75-45-6 LM1 0.9680499 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 23.1874987 -9.7681293 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0248487 -0.2409738 0.6122444 -0.7540744 0.3490911 0.0000000 ! ?R32 /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 351.255 8.15008 369.295 6.05822 75-10-5 /75-45-6 LM1 0.9859795 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -0.2966468 -1.5809202 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0156346 -0.0296609 0.0303644 0.0000000 0.0000000 0.0000000 ! ?R22 /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 487.210 2.98866 75-45-6 /76-13-1 LM1 0.9362645 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 79.7658744 -55.7488967 39.4369941 0.0000000 0.0000000 0.0000000 VC1 0.0398710 -0.3820472 0.6201195 -0.2820832 0.0000000 0.0000000 ! ?R22 /R114 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 418.830 3.39320 75-45-6 /76-14-2 LM1 0.9422711 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 33.1796703 -106.2615 144.8137 -72.0700451 0.0000000 0.0000000 VC1 0.0649068 -0.1645133 0.1613722 0.0000000 0.0000000 0.0000000 ! ?R22 /R115 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 353.100 3.96914 75-45-6 /76-15-3 LM1 0.8879426 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -33.5755569 -22.9131738 19.0838899 0.0000000 0.0000000 0.0000000 VC1 0.0285494 0.1086120 -0.3767298 0.1929928 0.0000000 0.0000000 ! ?R22 /R124 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 395.425 4.10332 75-45-6 /2837-89-0 LM1 0.9512546 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -1.1220145 -12.3584278 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0608392 -0.1823475 0.2538186 -0.0869575 0.0000000 0.0000000 ! ?R125 /R22 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 339.330 4.75996 369.295 6.05822 354-33-6 /75-45-6 LM1 0.9533869 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -13.0099133 -4.1885369 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0250361 0.0266109 -0.0032523 0.0000000 0.0000000 0.0000000 ! ?R22 /R134a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 374.180 4.97883 75-45-6 /811-97-2 LM1 0.9814663 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -4.2700377 -2.8001698 0.9594773 0.0000000 0.0000000 0.0000000 VC1 0.0006882 0.0272967 -0.0208942 0.0000000 0.0000000 0.0000000 ! ?R22 /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 410.250 4.32857 75-45-6 /75-68-3 LM1 1.0005794 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 15.8715116 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0006965 -0.0078383 0.0223985 0.0000000 0.0000000 0.0000000 ! ?R22 /R152a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 369.295 6.05822 386.411 5.57145 75-45-6 /75-37-6 LM1 1.0187319 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 9.0664552 2.4598197 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0956467 -0.6687868 2.3344727 -4.1558385 3.6369259 -1.2352840 ! ?R23 /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 487.210 2.98866 75-46-7 /76-13-1 LM1 0.8389275 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 213.6127 -193.8879 61.6247138 0.0000000 0.0000000 0.0000000 VC1 0.0179021 -0.8048106 1.0647166 -0.3981154 0.0000000 0.0000000 ! ?R23 /R114 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 418.830 3.39320 75-46-7 /76-14-2 LM1 0.8384995 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 108.7424 -141.8079 41.4569681 0.0000000 0.0000000 0.0000000 VC1 0.1211171 -0.9242969 1.3855654 -0.5789420 0.0000000 0.0000000 ! ?R23 /R116 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 299.070 7.49900 293.030 4.50692 75-46-7 /76-16-4 LM1 0.8270057 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -38.0703353 -23.8191702 -18.9427963 43.9533982 0.0000000 0.0000000 VC1 -0.0705002 0.4743236 -0.8217513 0.4041563 0.0000000 0.0000000 ! ?R32 /R115 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 351.255 8.15008 353.100 3.96914 75-10-5 /76-15-3 LM1 0.7615286 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -40.6423668 -82.3340033 -16.6564360 64.9807766 0.0000000 0.0000000 VC1 0.0428694 0.2801873 -3.8040137 13.9455741 -19.1465905 8.6512834 ! ?R32 /R152a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 351.255 8.15008 386.411 5.57145 75-10-5 /75-37-6 LM1 0.9928312 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 10.9621215 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0996973 -0.5386556 1.3786678 -1.6120752 0.7124290 0.0000000 ! ?R114 /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 418.830 3.39320 487.210 2.98866 76-14-2 /76-13-1 LM1 1.0005309 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 24.4581055 -23.0809771 34.7095645 0.0000000 0.0000000 0.0000000 VC1 -0.0241500 0.0793080 -0.2090658 0.1779739 0.0000000 0.0000000 ! ?R142b /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 410.250 4.32857 487.210 2.98866 75-68-3 /76-13-1 LM1 0.9606785 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 24.3328250 -10.9402571 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0106945 -0.0690868 0.0543547 0.0000000 0.0000000 0.0000000 ! ?R152a /R113 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 386.411 5.57145 487.210 2.98866 75-37-6 /76-13-1 LM1 0.8795149 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 48.0516839 -65.6797702 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0109357 -0.2067691 0.3016263 0.0000000 0.0000000 0.0000000 ! ?R115 /R114 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 353.100 3.96914 418.830 3.39320 76-15-3 /76-14-2 LM1 0.9944417 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 32.8751010 -45.1034802 32.3834418 0.0000000 0.0000000 0.0000000 VC1 0.0509991 -0.3501806 0.7222267 -0.6931983 0.1909052 0.0000000 ! ?R116 /R134a fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 293.030 4.50692 374.180 4.97883 76-16-4 /811-97-2 LM1 0.8717034 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 21.5701481 -88.9949814 29.0012708 0.0000000 0.0000000 0.0000000 VC1 -0.0492133 -0.3007543 0.4519632 -0.2056791 0.0000000 0.0000000 ! ?R134a /R123 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 374.180 4.97883 456.831 3.59642 811-97-2 /306-83-2 LM1 0.9477111 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 30.8264532 -24.2432576 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0101322 -0.0909839 0.0711306 0.0000000 0.0000000 0.0000000 ! ?R134a /R124 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 374.180 4.97883 395.425 4.10332 811-97-2 /2837-89-0 LM1 0.9741957 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -3.0723587 -4.8851480 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0264284 -0.1040416 0.1981314 -0.1308054 0.0000000 0.0000000 ! ?R124 /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 395.425 4.10332 410.250 4.32857 2837-89-0 /75-68-3 LM1 0.9963822 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -0.9801989 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0029319 0.0062550 -0.0163220 0.0139246 0.0000000 0.0000000 ! ?R152a /R124 fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 386.411 5.57145 395.425 4.10332 75-37-6 /2837-89-0 LM1 0.9877818 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -2.0119434 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0206975 0.0429417 -0.1726031 0.1819809 0.0000000 0.0000000 ! ?R134a /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 374.180 4.97883 410.250 4.32857 811-97-2 /75-68-3 LM1 0.9717736 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 0.8909094 -8.0704879 0.0000000 0.0000000 0.0000000 0.0000000 VC1 -0.0123969 -0.0119303 0.0667125 -0.0585442 0.0000000 0.0000000 ! ?R152a /R142b fitted to literature VLE data, 11-07-97 ?zeta,xi from Lemmon (NIST 1997) converted to Kt,Kv using reducing T and rho of: 386.411 5.57145 410.250 4.32857 75-37-6 /75-68-3 LM1 0.9664245 1.0000000 0.0000000 1.0000000 1.0000000 0.0000000 TC1 -4.2803359 -6.7602869 0.0000000 0.0000000 0.0000000 0.0000000 VC1 0.0038719 -0.0380872 0.0784565 0.0000000 0.0000000 0.0000000 ! #MXM !mixture model specification LM1 Lemmon & Jacobsen model for mixtures ?LITERATURE REFERENCE\ ?Lemmon, E.W. (1996). A generalized model for the prediction of the ? thermodynamic properties of mixtures including vapor-liquid equilibrium. ? PhD Thesis, Universtiy of Idaho, Moscow, ID. ? ?A mixture Helmholtz free energy (HMX) model for mixtures of hydrocarbons, ? simple inorganics, and refrigerants employing a generalized mixture function ? and binary-specific parameters Fpq, zeta, xi, and beta. The generalized ? mixture function is based on experimental data for 28 binary pairs:\ ?\ ? methane/ethane methane/propane methane/butane \ ? methane/isobutane methane/nitrogen methane/carbon dioxide \ ? methane/argon methane/ethene ethane/propane \ ? ethane/butane ethane/nitrogen ethane/carbon dioxide \ ? propane/butane propane/isobutane propane/nitrogen \ ? propane/carbon dioxide butane/isobutane butane/nitrogen \ ? nitrogen/carbon dioxide nitrogen/argon nitrogen/oxygen \ ? argon/oxygen argon/carbon dioxide neon/carbon dioxide \ ? R32/125 R32/134a R125/134a \ ? R134a/152a \ ?\ ?This implementation of the mixing rule transforms the zeta and xi of the ?original work to a simple linear mixing rule using Kt and Kv (LIN model). ? !end of info section Kt Kv Fpq beta gamma not used !descriptors for binary-specific parameters 1.00 1.00 0.00 1.00 1.00 0.00 !default values (i.e. ideal-solution) 10 3 0 !Nterm, Nxcoef, Nicoef per term -0.245476271425d-1 2.00 1.00 !a(i),t(i),d(i) -0.241206117483d+0 4.00 1.00 -0.513801950309d-2 -2.00 1.00 -0.239824834123d-1 1.00 2.00 0.259772344008d+0 4.00 3.00 -0.172014123104d+0 4.00 4.00 0.429490028551d-1 4.00 5.00 -0.202108593862d-3 0.00 6.00 -0.382984234857d-2 4.00 6.00 0.262992331354d-5 -2.00 8.00 #MXM !mixture model specification LM2 Lemmon & Jacobsen model for R32/125 mixtures ?LITERATURE REFERENCE\ ?Lemmon, E.W. (1996). A generalized model for the prediction of the ? thermodynamic properties of mixtures including vapor-liquid equilibrium. ? PhD Thesis, Universtiy of Idaho, Moscow, ID. ? ?A mixture Helmholtz free energy (HMX) model for mixtures of hydrocarbons, ? simple inorganics, and refrigerants employing a generalized mixture function ? and binary-specific parameters Fpq, zeta, xi, and beta. The generalized ? mixture function is based on experimental data for 28 binary pairs:\ ?\ ? methane/ethane methane/propane methane/butane \ ? methane/isobutane methane/nitrogen methane/carbon dioxide \ ? methane/argon methane/ethene ethane/propane \ ? ethane/butane ethane/nitrogen ethane/carbon dioxide \ ? propane/butane propane/isobutane propane/nitrogen \ ? propane/carbon dioxide butane/isobutane butane/nitrogen \ ? nitrogen/carbon dioxide nitrogen/argon nitrogen/oxygen \ ? argon/oxygen argon/carbon dioxide neon/carbon dioxide \ ? R32/125 R32/134a R125/134a \ ? R134a/152a \ ?\ ?This model differs from the more general Lemmon-Jacobsen model (LJ1/LM1) by ? the addition of two terms specific to the R32/125 binary. ?\ ?This implementation of the mixing rule transforms the zeta and xi of the ? original work to a simple linear mixing rule using Kt and Kv (LIN model). ? In addition, the N11 and N12 from Lemmon's thesis are divided by Fpq for ? R32/125 to transform this model into the more general LM1 form. ? !end of info section Kt Kv Fpq beta gamma not used !descriptors for binary-specific parameters 1.00 1.00 0.00 1.00 1.00 0.00 !default values (i.e. ideal-solution) 12 3 0 !Nterm; Nxcoef, Nicoef per term -0.245476271425d-1 2.00 1.00 !a(i),t(i),d(i) -0.241206117483d+0 4.00 1.00 -0.513801950309d-2 -2.00 1.00 -0.239824834123d-1 1.00 2.00 0.259772344008d+0 4.00 3.00 -0.172014123104d+0 4.00 4.00 0.429490028551d-1 4.00 5.00 -0.202108593862d-3 0.00 6.00 -0.382984234857d-2 4.00 6.00 0.262992331354d-5 -2.00 8.00 0.251532425085d-1 1.00 1.00 !additional terms specific to R32/125 -0.181394597776d+0 0.00 1.00 != (Ni of Lemmon)/Fpq #MXM !mixture model specification LM3 Lemmon & Jacobsen model for R32/134a mixtures ?LITERATURE REFERENCE\ ?Lemmon, E.W. (1996). A generalized model for the prediction of the ? thermodynamic properties of mixtures including vapor-liquid equilibrium. ? PhD Thesis, Universtiy of Idaho, Moscow, ID. ? ?A mixture Helmholtz free energy (HMX) model for mixtures of hydrocarbons, ? simple inorganics, and refrigerants employing a generalized mixture function ? and binary-specific parameters Fpq, zeta, xi, and beta. The generalized ? mixture function is based on experimental data for 28 binary pairs:\ ?\ ? methane/ethane methane/propane methane/butane \ ? methane/isobutane methane/nitrogen methane/carbon dioxide \ ? methane/argon methane/ethene ethane/propane \ ? ethane/butane ethane/nitrogen ethane/carbon dioxide \ ? propane/butane propane/isobutane propane/nitrogen \ ? propane/carbon dioxide butane/isobutane butane/nitrogen \ ? nitrogen/carbon dioxide nitrogen/argon nitrogen/oxygen \ ? argon/oxygen argon/carbon dioxide neon/carbon dioxide \ ? R32/125 R32/134a R125/134a \ ? R134a/152a \ ?\ ?This model differs from the more general Lemmon-Jacobsen model (LJ1/LM1) by ? the addition of one term specific to the R32/134a binary. ?\ ?This implementation of the mixing rule transforms the zeta and xi of the ? original work to a simple linear mixing rule using Kt and Kv (LIN model). ? In addition, the N13 from Lemmon's thesis is divided by Fpq for R32/134a to ? transform this model into the more general LM1 form. ? !end of info section Kt Kv Fpq beta gamma not used !descriptors for binary-specific parameters 1.00 1.00 0.00 1.00 1.00 0.00 !default values (i.e. ideal-solution) 11 3 0 !Nterm; Nxcoef, Nicoef per term -0.245476271425d-1 2.00 1.00 !a(i),t(i),d(i) -0.241206117483d+0 4.00 1.00 -0.513801950309d-2 -2.00 1.00 -0.239824834123d-1 1.00 2.00 0.259772344008d+0 4.00 3.00 -0.172014123104d+0 4.00 4.00 0.429490028551d-1 4.00 5.00 -0.202108593862d-3 0.00 6.00 -0.382984234857d-2 4.00 6.00 0.262992331354d-5 -2.00 8.00 -0.117335612626d+0 0.00 1.00 !R32/134a-specific term = (N13/Fpq) #MXM !mixture model specification LM9 Lemmon & Jacobsen model for R41/CO2 mixtures ?LITERATURE REFERENCE\ ?Lemmon, E.W. (1996). A generalized model for the prediction of the ? thermodynamic properties of mixtures including vapor-liquid equilibrium. ? PhD Thesis, Universtiy of Idaho, Moscow, ID. ? ?A mixture Helmholtz free energy (HMX) model for mixtures of hydrocarbons, ? simple inorganics, and refrigerants employing a generalized mixture function ? and binary-specific parameters Fpq, zeta, xi, and beta. The generalized ? mixture function is based on experimental data for 28 binary pairs:\ ?\ ? methane/ethane methane/propane methane/butane \ ? methane/isobutane methane/nitrogen methane/carbon dioxide \ ? methane/argon methane/ethene ethane/propane \ ? ethane/butane ethane/nitrogen ethane/carbon dioxide \ ? propane/butane propane/isobutane propane/nitrogen \ ? propane/carbon dioxide butane/isobutane butane/nitrogen \ ? nitrogen/carbon dioxide nitrogen/argon nitrogen/oxygen \ ? argon/oxygen argon/carbon dioxide neon/carbon dioxide \ ? R32/125 R32/134a R125/134a \ ? R134a/152a \ ?\ ?This model differs from the more general Lemmon-Jacobsen model (LJ1/LM1) by ? the addition of one term specific to the R41/CO2 binary. ?\ ?This implementation of the mixing rule transforms the zeta and xi of the ? original work to a simple linear mixing rule using Kt and Kv (LIN model). ? In addition, the N14 from Lemmon is divided by Fpq for R41/CO2 to ? transform this model into the more general LMx form. ? !end of info section Kt Kv Fpq beta gamma not used !descriptors for binary-specific parameters 1.00 1.00 0.00 1.00 1.00 0.00 !default values (i.e. ideal-solution) 11 3 0 !Nterm; Nxcoef, Nicoef per term -0.245476271425d-1 2.00 1.00 !a(i),t(i),d(i) -0.241206117483d+0 4.00 1.00 -0.513801950309d-2 -2.00 1.00 -0.239824834123d-1 1.00 2.00 0.259772344008d+0 4.00 3.00 -0.172014123104d+0 4.00 4.00 0.429490028551d-1 4.00 5.00 -0.202108593862d-3 0.00 6.00 -0.382984234857d-2 4.00 6.00 0.262992331354d-5 -2.00 8.00 -0.250438530000d+0 0.00 1.00 !R41/CO2-specific term = (N14/Fpq) #MXM !mixture model specification LJ1 Lemmon & Jacobsen model for mixtures ?LITERATURE REFERENCE\ ?Lemmon, E.W. (1996). A generalized model for the prediction of the ? thermodynamic properties of mixtures including vapor-liquid equilibrium. ? PhD Thesis, Universtiy of Idaho, Moscow, ID. ? ?A mixture Helmholtz free energy (HMX) model for mixtures of hydrocarbons, ? simple inorganics, and refrigerants employing a generalized mixture function ? and binary-specific parameters Fpq, zeta, xi, and beta. The generalized ? mixture function is based on experimental data for 28 binary pairs:\ ?\ ? methane/ethane methane/propane methane/butane \ ? methane/isobutane methane/nitrogen methane/carbon dioxide \ ? methane/argon methane/ethene ethane/propane \ ? ethane/butane ethane/nitrogen ethane/carbon dioxide \ ? propane/butane propane/isobutane propane/nitrogen \ ? propane/carbon dioxide butane/isobutane butane/nitrogen \ ? nitrogen/carbon dioxide nitrogen/argon nitrogen/oxygen \ ? argon/oxygen argon/carbon dioxide neon/carbon dioxide \ ? R32/125 R32/134a R125/134a \ ? R134a/152a \ ? !end of info section zeta xi Fpq beta gamma not used !descriptors for binary-specific parameters 0.00 0.00 0.00 1.00 1.00 0.00 !default values (i.e. ideal-solution) 10 3 0 !Nterm, Nxcoef, Nicoef per term -0.245476271425d-1 2.00 1.00 !a(i),t(i),d(i) -0.241206117483d+0 4.00 1.00 -0.513801950309d-2 -2.00 1.00 -0.239824834123d-1 1.00 2.00 0.259772344008d+0 4.00 3.00 -0.172014123104d+0 4.00 4.00 0.429490028551d-1 4.00 5.00 -0.202108593862d-3 0.00 6.00 -0.382984234857d-2 4.00 6.00 0.262992331354d-5 -2.00 8.00 #MXM !mixture model specification LIN linear mixing rules modified by Kt and Kv ?LITERATURE REFERENCE\ ?McLinden, M.O. and Klein, S.A. (1996). A next generation refrigerant ? properties database. 6th International Refrigeration Conference at Purdue, ? July 23-26, West Lafayette, IN. \ ?\ ?A mixture Helmholtz free energy (HMX) model for refrigerant mixtures employing ? simple linear mixing rules to define the reducing parameters. The parameter ? Kt is applied to the arithmetic mean of the component critical temperatures: \ ?\ ? Treducing = sum(i=1,n) {xi * Tcrit_i} ? + sum(j=i+1,n) sum(i=1,n-1) {(Kt - 1) xi xj 0.5*(Tcrit_i + Tcrit_j)} \ ?\ ?and the parameter Kv is similarly applied to the arithmetic mean of the ? component critical volumes: \ ?\ ? Vreducing = sum(i=1,n) {xi * Vcrit_i} ? + sum(j=i+1,n) sum(i=1,n-1) {(Kv - 1) xi xj 0.5*(Vcrit_i + Vcrit_j)} \ ?\ ? rho_reducing = 1/Vreducing. ? !end of info section Kt Kv not used not used not used not used !descriptors for binary-specific parameters 1.00 1.00 0.00 0.00 0.00 0.00 !default values (i.e. ideal-solution) 1 3 1 !Nterm; Nxcoef, Nicoef per term 1.00d0 0.00d0 1.00d0 0 !a(i),t(i),d(i),l(i) (dummy values) @MXM !mixture model specification i=j trivial case--identical components ?DESCRIPTION ?This represents the trivial mixture case of identical components. It is ? included for use with some of the summations involved in mixture calculations. ? This model should not be specified for any binary pair. ? !end of info section not used not used not used not used not used not used !descriptors for binary-specific parameters 0.00 0.00 0.00 0.00 0.00 0.00 !default values (i.e. ideal-solution) 1 3 1 !Nterm; Nxcoef, Nicoef per term 1.00d0 0.00d0 1.00d0 0 !a(i),t(i),d(i),l(i) (dummy values) @END c 1 2 3 4 5 6 7 8 c2345678901234567890123456789012345678901234567890123456789012345678901234567890